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Synlett 1995; 1995(5): 445-446
DOI: 10.1055/s-1995-4992
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Asymmetric Addition of Organometallic Reagents to O-Phenethyl Aldoximes

Peter T. Gallagher, Andrew P. Lightfood, Christopher J. Moody* , Alexandra M. Z. Slawin
  • *Department of Chemistry, University of Loughborough, Loughborough LE11 3TU, UK
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Publication Date:
31 December 2000 (online)

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Addition of Grignard and organolithium reagents to O-phenethyl aldoximes in the presence of boron trifluoride etherate gives secondary hydroxylamines in 21-84% yield with 38-95% diastereomeric excess.

asymmetric addition - chiral oxime ether - hydroxylamine

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