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Synlett 1995; 1995(2): 145-146
DOI: 10.1055/s-1995-4900
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Intramolecular Photochemical [2+2] Cycloadditions of Enantiomerically Pure 4,4-Disubstituted Cyclohexenones: An Approach to the Total Asymmetric Synthesis of Lintenone

James E. Resek, A. I. Meyers*
  • *Department of Chemistry, Colorado State University, Fort Collins, CO 80523, U.S.A.
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Publication Date:
31 December 2000 (online)

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Enantiomerically pure 4,4-dialkylcyclohexenones 12-14 have been prepared which undergo photochemical [2+2] cycloadditions to give the ring system of lintenone 1.

chiral lactam - alkyl lithiums - carbinol amides - amide enolates - alkylation

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