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Synlett 1994; 1994(12): 993-994
DOI: 10.1055/s-1994-23071
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Functional Group Elaboration for Taxol C-Ring: γ-Enolization of the α,β-Enone Directed by the Hydroxy Group

Masaki Seto* , Kazuyoshi Sakurai, Yoshiaki Horiguchi, Isao Kuwajima
  • *Department of Chemistry, Tokyo Institute of Technology, Meguro, Tokyo 152, Japan
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Publication Date:
22 March 2002 (online)

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A method for γ-enolization of α,β-enones by means of directing effect of a neighboring hydroxy group has been established. Such a method, coupled with subsequent installation of a hydroxy group at the γ-position, would serve as an efficient tool for functional group elaboration on taxol C-ring.

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