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Synlett 1993; 1993(11): 850-852
DOI: 10.1055/s-1993-22630
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Conversion of Esters to Amides with Amino Halo Stannylenes

Laura A. Smith* , Wei-Bo Wang, Cynthia Burnell-Curty, Eric J. Roskamp
  • *Department of Chemistry, Northwestern University, Evanston, Illinois 60208, USA
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Publication History

Publication Date:
19 March 2002 (online)

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Amino chloro stannylenes have been prepared in situ using two different procedures: (1) reaction of an amine hydrochloride with Sn[N(TMS)2]2 and (2) reaction of a tin(II) amide with tin(II) chloride. These reagents are useful for the conversion of primary, α,β-unsaturated, or aromatic esters to amides.

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