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Synlett 1993; 1993(11): 833-834
DOI: 10.1055/s-1993-22623
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Asymmetric Cyclopropanation Catalyzed by Chiral Cobalt(II) Complexes from (1R)-3-Hydroxymethylene-Bornane-2-Thione.

Giancarlo Jommi* , Roberto Pagliarin, Gianfranco Rizzi, Massimo Sisti
  • *Università degli Studi di Milano - Dipartimento di Chimica Organica e Industriale - Via G. Venezian, 21 -20133 Milano Italy
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Publication Date:
19 March 2002 (online)

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The Co(II) complex 3, derived from (1R)-3-hydroxymethylene-bornane-2-thione and ethylenediamine was used as chiral catalyst for the asymmetric cyclopropanation of styrene and 1-octene by ethyl diazoacetate.

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