Download PDF
Synlett 1993; 1993(9): 689-690
DOI: 10.1055/s-1993-22573
letter
© Georg Thieme Verlag, Rüdigerstr. 14, 70469 Stuttgart, Germany. All rights reserved. This journal, including all individual contributions and illustrations published therein, is legally protected by copyright for the duration of the copyright period. Any use, exploitation or commercialization outside the narrow limits set by copyright legislation, without the publisher's consent, is illegal and liable to criminal prosecution. This applies in particular to photostat reproduction, copying, cyclostyling, mimeographing or duplication of any kind, translating, preparation of microfilms, and electronic data processing and storage.

Copper-Catalyzed SN2′-Selective Cross Coupling Reaction Between Grignard Reagents and Allylic Phosphates

Akira Yanagisawa* , Nobuyoshi Nomura, Hisashi Yamamoto
  • *School of Engineering, Nagoya University, Chikusa, Nagoya 464-01, Japan
Further Information

Publication History

Publication Date:
19 March 2002 (online)

  PDF Download  Permissions and Reprints All articles of this category

The SN2′-selective Grignard coupling with primary allylic diphenylphosphates was successfully achieved in the presence of a catalytic amount of CuCN·2LiCl. γ-Substituted allyl Grignard reagents reacted with allylic phosphates selectively at the less substituted allylic terminus.

      >