Highly γ-Selective Coupling of Siloxyallylbarium Reagent with Carbonyl Compounds and Alkyl Halides

Akira Yanagisawa; Katsutaka Yasue; Hisashi Yamamoto

doi:10.1055/s-1993-22572

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Synlett 1993; 1993(9): 686-688
DOI: 10.1055/s-1993-22572

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Highly γ-Selective Coupling of Siloxyallylbarium Reagent with Carbonyl Compounds and Alkyl Halides

Akira Yanagisawa^* , Katsutaka Yasue, Hisashi Yamamoto

^*School of Engineering, Nagoya University, Chikusa, Nagoya 464-01, Japan

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Publication Date:
19 March 2002 (online)

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Siloxyallylbarium reagents, prepared from anhydrous BaI₂ and siloxyallyllithium, reacted with carbonyl compounds and alkyl halides highly selectively at the γ-position in high yields.

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