A Highly Efficient Kinetic Resolution of ω-Trimethylsilyl Polyunsaturated  Secondary Alcohols by Lipase-Catalyzed Transesterification

Vito Fiandanese; Omar Hassan; Francesco Naso; Antonio Scilimati

doi:10.1055/s-1993-22502

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Synlett 1993; 1993(7): 491-493
DOI: 10.1055/s-1993-22502

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A Highly Efficient Kinetic Resolution of ω-Trimethylsilyl Polyunsaturated Secondary Alcohols by Lipase-Catalyzed Transesterification

Vito Fiandanese^* , Omar Hassan, Francesco Naso, Antonio Scilimati

^*Centro CNR di Studio sulle Metodologie Innovative di Sintesi Organiche, Dipartimento di Chimica, Università di Bari, Via Amendola 173, I-70126 Bari, Italy

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Publication Date:
19 March 2002 (online)

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A high (>97%) enantioselectivity was observed in the lipase catalyzed transesterification of vinyl acetate with conjugated polyunsaturated secondary alcohols.

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