α-Alkylation of α,α-Disubstituted Amines via η2-Ketimine Complexes of Zirconocene

Nicholas Coles; Richard J. Whitby; Julian Blagg

doi:10.1055/s-1992-21993

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Synlett 1992; 1992(2): 143-145
DOI: 10.1055/s-1992-21993

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α-Alkylation of α,α-Disubstituted Amines via η²-Ketimine Complexes of Zirconocene

Nicholas Coles^* , Richard J. Whitby, Julian Blagg

^*Chemistry Department, The University, Southampton SO9 5NH, England

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Publication Date:
08 March 2002 (online)

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η²-Ketimine complexes of zirconocene can be generated by a C-H activation process from α,α-disubstituted amines and react with a variety of unsaturated substrates to afford α-trisubstituted amines.

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