Download PDF
Synlett 1992; 1992(12): 973-975
DOI: 10.1055/s-1992-21550
letter
© Georg Thieme Verlag, Rüdigerstr. 14, 70469 Stuttgart, Germany. All rights reserved. This journal, including all individual contributions and illustrations published therein, is legally protected by copyright for the duration of the copyright period. Any use, exploitation or commercialization outside the narrow limits set by copyright legislation, without the publisher's consent, is illegal and liable to criminal prosecution. This applies in particular to photostat reproduction, copying, cyclostyling, mimeographing or duplication of any kind, translating, preparation of microfilms, and electronic data processing and storage.

Stereospecific Synthesis of Vinylsilanes via Trimethylsilyl-Substituted Allyliron Cations

Christopher Gajda* , James R. Green
  • *Department of Chemistry and Biochemistry, University of Windsor, Windsor, Ontario, N9B 3P4, Canada
Further Information

Publication History

Publication Date:
08 March 2002 (online)

  PDF Download  Permissions and Reprints All articles of this category

The reaction of trimethylsilyl substituted anti- and syn-allyltetracarbonyliron complexes with silyl enol ethers, silyl ketene acetals, or allyltin compounds affords Z- and E-vinylsilanes, respectively, with a high degree of stereochemical purity.

      >