Download PDF
Synlett 1992; 1992(11): 878-880
DOI: 10.1055/s-1992-21525
letter
© Georg Thieme Verlag, Rüdigerstr. 14, 70469 Stuttgart, Germany. All rights reserved. This journal, including all individual contributions and illustrations published therein, is legally protected by copyright for the duration of the copyright period. Any use, exploitation or commercialization outside the narrow limits set by copyright legislation, without the publisher's consent, is illegal and liable to criminal prosecution. This applies in particular to photostat reproduction, copying, cyclostyling, mimeographing or duplication of any kind, translating, preparation of microfilms, and electronic data processing and storage.

A Facile Synthesis of 2-exo-Methylenepenam Through Reductive Cyclization of Allenecarboxylates in a Metal Salt/Metal Bimetal Redox System

Hideo Tanaka* , Yutaka Kameyama, Sigeru Torii
  • *Department of Applied Chemistry, Faculty of Engineering, Okayama University, Okayama 700, Japan
Further Information

Publication History

Publication Date:
08 March 2002 (online)

  PDF Download  Permissions and Reprints All articles of this category

Construction of the 2-exo-methylenepenam framework has been performed successfully by reductive cyclization of 2-(4-phenylsulfonylthio-2-oxoazetidin-1-yl)-2, 3-butadienoates, derived from penicillin G, in a bismuth(III) chloride/zinc bimetal redox system.

      >