Efficient Asymmetric Hydrogenation of γ-Amino Ketone Hydrochloride Derivatives Catalyzed by (2S,4S)-4-Dicyclohexylphosphino-2-diphenylphosphinomethyl-1-(N-methylcarbamoyl)-pyrrolidine(MCCPM)-Rhodium complex1

Shunji Sakuraba; Noriya Nakajima; Kazuo Achiwa

doi:10.1055/s-1992-21507

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Synlett 1992; 1992(10): 829-830
DOI: 10.1055/s-1992-21507

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Efficient Asymmetric Hydrogenation of γ-Amino Ketone Hydrochloride Derivatives Catalyzed by (2S,4S)-4-Dicyclohexylphosphino-2-diphenylphosphinomethyl-1-(N-methylcarbamoyl)-pyrrolidine(MCCPM)-Rhodium complex¹

Shunji Sakuraba^* , Noriya Nakajima, Kazuo Achiwa

^*School of Pharmaceutical Sciences, University of Shizuoka, 52-1 Yada, Shizuoka 422, Japan

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Publication Date:
08 March 2002 (online)

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The title complex, (2S,4S)-MCCPM-Rh(I) complex, was found to be an efficient catalyst for asymmetric hydrogenation of γ-amino ketone hydrochloride derivatives.

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