Synlett 1992; 1992(8): 638-640
DOI: 10.1055/s-1992-21439
letter
© Georg Thieme Verlag, Rüdigerstr. 14, 70469 Stuttgart, Germany. All rights reserved. This journal, including all individual contributions and illustrations published therein, is legally protected by copyright for the duration of the copyright period. Any use, exploitation or commercialization outside the narrow limits set by copyright legislation, without the publisher's consent, is illegal and liable to criminal prosecution. This applies in particular to photostat reproduction, copying, cyclostyling, mimeographing or duplication of any kind, translating, preparation of microfilms, and electronic data processing and storage.

Reactions of Dibenzyl Diselenides with Alkali Metal Hydrides

Alain Krief* , Mahmoud Trabelsi, Willy Dumont
  • *Facultés Universitaires Notre-Dame de la Paix, Department of Chemistry, 61 rue de Bruxelles, B-5000 Namur, Belgium
Further Information

Publication History

Publication Date:
08 March 2002 (online)

Sodium and potassium hydrides in dimethylformamide react on the benzylic hydrogens of dibenzyl diselenides and lead, depending upon the structure of the starting material, to a large variety of compounds. The formation of most of them is compatible with the intermediary formation of a selone. All our efforts aimed to isolate or to trap such an intermediate proved to be unsuccessful.

    >