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Synlett 1992; 1992(7): 579-581
DOI: 10.1055/s-1992-21422
DOI: 10.1055/s-1992-21422
letter
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New Efficient Synthesis of 1-Aminocyclopropanecarboxylic Acid
Further Information
Publication History
Publication Date:
08 March 2002 (online)
Methyl 2-[bis(methylthio)methyleneamino]acrylate (1) was efficiently converted into methyl 1-[bis(methylthio)-methyleneamino]cyclopropanecarboxylate (3) by reaction with diazomethane. This transformation provides a novel and efficient route to 1-aminocyclopropanecarboxylic acid (ACC), which is found in many plants.