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Synlett 1992; 1992(5): 444-446
DOI: 10.1055/s-1992-21375
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Total Synthesis of (±)-Acerosolide

Peter C. Astles* , Leo A. Paquette
  • *Evans Chemical Laboratories, The Ohio State University, Columbus, Ohio 43210, USA
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Publication History

Publication Date:
08 March 2002 (online)

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A stereocontrolled total synthesis of acerosolide (1), a fourteen-membered furanocembranolide produced by the Caribbean gorgonian Pseudopterogorgia acerosa, has been accomplished by a concise series of reactions featuring a regioreversed allylstannane condensation and an intramolecular chromium(II) chloride-promoted macrocyclization.

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