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Synlett 1991; 1991(3): 155-156
DOI: 10.1055/s-1991-20660
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Allylsilanes by the Regio- and Stereocontrolled Substitution of Metalated Homoallylsilanes

A. Degl'Innocenti* , A. Mordini, L. Pagliai, A. Ricci
  • *Centro CNR sulla Struttura dei Composti Eterociclici e loro Applicazione, c/o Dipartimento di Chimica Organica U. Schiff, via G. Capponi 9, I-50121 Firenze, Italy
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Publication Date:
07 March 2002 (online)

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The metalation of homoallylsilane 1 (4-trimethylsilyl-1-butene) with butyllithium/potassium tert-butoxide followed by quenching with electrophiles (7 examples) leads under mild conditions and with satisfactory yield to a series of 3-substituted allylsilanes [(Z)-2-alkenyltrimethylsilanes].

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