Download PDF
Synlett 1990; 1990(12): 759-761
DOI: 10.1055/s-1990-21242
letter
© Georg Thieme Verlag, Rüdigerstr. 14, 70469 Stuttgart, Germany. All rights reserved. This journal, including all individual contributions and illustrations published therein, is legally protected by copyright for the duration of the copyright period. Any use, exploitation or commercialization outside the narrow limits set by copyright legislation, without the publisher's consent, is illegal and liable to criminal prosecution. This applies in particular to photostat reproduction, copying, cyclostyling, mimeographing or duplication of any kind, translating, preparation of microfilms, and electronic data processing and storage.

Enantioselective Allylboration of Aldehydes with (4R,5R)-2-[(S)-1-chloro-2-propenyl]-4, 5-dicyclohexyl-1,3,2-dioxaborolane

Rainer Stürmer* , Reinhard W. Hoffmann
  • *Fachbereich Chemie der Philipps-Universität Marburg, Hans-Meerwein-Strasse, D-3550 Marburg a.d. Lahn, Germany
Further Information

Publication History

Publication Date:
08 March 2002 (online)

  PDF Download  Permissions and Reprints All articles of this category

The title compound, chiral 1-chloro-2-propenylboronate 1a, adds to aldehydes to give the homoallyl alcohols 2 in 75-90 % yield with complete (>99 %) transfer of chirality.

      >