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Synlett 1990; 1990(11): 679-680
DOI: 10.1055/s-1990-21209
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Synthesis of 4-Oxoaldehydes by the Ceric Ammonium Nitrate Promoted Oxidative Addition of Trimethylsilyl Enol Ethers to Ethyl Vinyl Ether

Enrico Baciocchi* , Angela Casu, Renzo Ruzziconi
  • *Dipartimento di Chimica Università "La Sapienza", I-00185 Roma, Italy
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Publication Date:
08 March 2002 (online)

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A variety of 3,4-disubstituted 4-oxoaldehydes can be prepared, in 54-80% yield, by the oxidative addition of 1,2-disubstituted trimethylsilyl enol ethers to ethyl vinyl ether promoted by cerium(IV) ammonium nitrate.

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