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Synthesis 1989; 1989(9): 706-709
DOI: 10.1055/s-1989-27368
DOI: 10.1055/s-1989-27368
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Synthesis of New Optically Active Bis- and Tris(phosphines)
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Publication History
Publication Date:
17 September 2002 (online)
The synthesis of new optically active alkanediylbis- and alkanetriyltris(diphenylphosphines) is described. Easily accessible optically pure lactones and carboxylic acids are reduced to the alcohols, tosylated and reacted with lithium diphenylphosphide to give the corresponding phosphines.