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Synthesis 1988; 1988(4): 344-345
DOI: 10.1055/s-1988-27569
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Nucleophilic Aromatic Substitution on Tricarbonyl(halogenoarene)chromium Complexes: A New Synthesis of O-Arylhydroxylamines

Clara Baldoli* , Paola Del Buttero, Emanuela Licandro, Stefano Maiorana
  • *Dipartimento di Chimica Organica e Industriale e Centro CNR dell'Universita', Via C. Golgi 19, I-20133 Milano, Italy
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Publication Date:
20 August 2002 (online)

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A series of O-arylhydroxylamines 4 have been synthesized under mild conditions and in good yields by the reaction of tricarbonyl(halogenoarene)chromium complexes 1 with N-(tert-butyloxycarbonyl)hydroxylamine (tert-butyl N-hydroxycarbamate), followed by decomplexation and acidic hydrolysis of the tert-butyl N-(aryloxy)carbamates 3.

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