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Synthesis 1987; 1987(9): 848-850
DOI: 10.1055/s-1987-28101
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Silylierte Amine II.1 Eine neue, variationsreiche Aminsynthese durch N,N-Bis(trimethylsilyl)aminomethylierung von Grignard-Verbindungen

Hans Jürgen Bestmann* , Gerhard Wölfel, Karl Mederer
  • *Institut für Organische Chemie der Universität Erlangen-Nürnberg, Henkestraße 42, D-8520 Erlangen, West Germany
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Publication Date:
12 September 2002 (online)

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Silylated Amines II. A New, Highly Variable Amine Synthesis by the N,N-Bis(trimethylsilyl)aminomethylation of Grignard Compounds Sodium bis(trimethylsilyl)amide reacts with chloromethyl methylether (1) to form methoxy-N,N-bis(trimethylsilyl)aminomethane (3), which effects the aminomethylation of Grignard compounds 4 to form N,N-bis(trimethylsilyl)amines 5.

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