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Synthesis 1986; 1986(8): 686-689
DOI: 10.1055/s-1986-31751
DOI: 10.1055/s-1986-31751
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Phasen-Transfer-Katalyse unter reduzierenden Bedingungen: Hydrochinon-dialkylether aus Chinonen
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Publication History
Publication Date:
22 August 2002 (online)
Phase-transfer Catalysis under Reductive Conditions: Hydroquinone Dialkyl Ethers from Quinones Hydroquinone ethers with alternant and nonalternant topology are prepared in one-pot reactions from the corresponding quinones by using sodium dithionite, sodium hydroxide, and alkylating reagents under phase-transfer conditions (Adogen 464). The use of allyl bromide leads to O- and C-allylation.