Download PDF
Synthesis 1969; 1969(3): 97-112
DOI: 10.1055/s-1969-34194
review
© Georg Thieme Verlag, Rüdigerstr. 14, 70469 Stuttgart, Germany. All rights reserved. This journal, including all individual contributions and illustrations published therein, is legally protected by copyright for the duration of the copyright period. Any use, exploitation or commercialization outside the narrow limits set by copyright legislation, without the publisher's consent, is illegal and liable to criminal prosecution. This applies in particular to photostat reproduction, copying, cyclostyling, mimeographing or duplication of any kind, translating, preparation of microfilms, and electronic data processing and storage.

The lsomerization of Olefins Part I. Base-Catalysed lsomerization of Olefins

A. J. HUBERT* , H. REIMLINGER
  • *Union Carbide European Research Associates S.A. 95, rue Gatti de Gamond, Brussels 18, Belgium
Further Information

Publication History

Publication Date:
19 September 2002 (online)

  PDF Download  Permissions and Reprints All articles of this category

Isomerization of olefinic and acetylenic compounds have received much attention during las few years both in their theoretical and in practical aspects. The methods used in isomerization of olefins (migration of the olefinic double bond) and related reactions are the subject of the this review; isomerizations involving rearrangement of the carbon skeleton are not considered. Part I deals with base-catalyzed isomerizations. Part II is concerned with isomerizations catalysed by acids, metal complexes, radicals, etc. The knowledge of the conditions under which isomerization of olefins occurs, is not only valuable for the conversion of olefins to their isomers, but is an important consideration when olefins are to be prepared by any other means. Under such conditions as here described an unwanted reaction product may be formed as a result of isomerization.

      >