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Synthesis 2021; 53(11): 2000-2006
DOI: 10.1055/s-0040-1705990
DOI: 10.1055/s-0040-1705990
paper
Development of a Novel Method for Trimethylsilylation of Saccharides
The authors thank the Ministry of Science and Technology (MOST) in Taiwan (MOST 107-2113-M-005-021) and National Chung Hsing University for financial support.
Abstract
The trimethylsilyl (TMS) group is widely used in carbohydrate synthesis, although this protecting group is unstable and its post-synthetic purification challenging. The successful trimethylsilylation of carbohydrates mediated by recyclable and efficient acidic catalyst PTA/HMDS and the novel reagent, TMSOAc (TEA/TMSOAc), under alkaline condition is reported. The advantages of these methods are that the reactions proceed in good to excellent yields without applying column chromatography for purification.
Key words
phosphotungstic acid - trimethylsilyl acetate - trimethylsilylation - recover - reused - catalysisSupporting Information
- Supporting information for this article is available online at https://doi.org/10.1055/s-0040-1705990.
- Supporting Information
Publication History
Received: 18 October 2020
Accepted after revision: 10 November 2020
Article published online:
19 January 2021
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