Nickel(II)- and Silver(I)-Catalyzed C–H Bond Halogenation of Anilides and Carbamates

Abstract

ortho-C–H bond halogenation of anilides and N-aryl carbamates using easily available N-halosuccinimides (NXS) as the active halogenation reagent in the presence of nickel or silver catalyst has been developed. This method provides a new approach to 2-haloanilides and carbamates, which may serve as starting materials for the synthesis of pharmaceutically and biologically active compounds.

Key words

cross-coupling reactions - C–H activation - homogeneous catalysis - halogenation - nickel - silver

Publication History

Received: 26 July 2020

Accepted after revision: 12 October 2020

Article published online:
30 November 2020

• References

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