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Synthesis 2017; 49(12): 2727-2732
DOI: 10.1055/s-0036-1588988
DOI: 10.1055/s-0036-1588988
paper
Stereoselective Synthesis of Vinyl Iodides through Copper(I)-Catalyzed Finkelstein-Type Halide-Exchange Reaction
Further Information
Publication History
Received: 25 February 2017
Accepted after revision: 10 March 2017
Publication Date:
11 April 2017 (online)
Abstract
An efficient method for the stereoselective synthesis of vinyl iodides is described. The reactions of vinyl bromides with potassium iodide proceed smoothly in the presence of a copper catalyst under mild reaction conditions to produce the corresponding vinyl iodides stereospecifically and in satisfactory to excellent yields.
Key words
stereoselective synthesis - vinyl iodides - vinyl bromides - copper catalyst - halide-exchange reactionSupporting Information
- Supporting information for this article is available online at http://dx.doi.org/10.1055/s-0036-1588988.
- Supporting Information
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For a book, see:
For the use of vinyl iodides in various coupling reactions, see:
For selected references, see:
For selected reviews, see:
For copper-mediated bromide–iodide exchange reactions, see:
For nickel-mediated bromide–iodide exchange reactions, see:
For copper-catalyzed bromide–iodide exchange reactions, see:
For nickel-catalyzed bromide–iodide exchange reactions, see:
Cu(I) salts and nitrogen-containing ligands were frequently utilized in C–C, C–N, and C–O coupling reactions. For books, see: