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Synthesis 2016; 48(09): 1399-1406
DOI: 10.1055/s-0035-1561366
DOI: 10.1055/s-0035-1561366
paper
Microwave-Promoted Deprenylation: Prenyl Ether as a Thermolabile Phenol Protecting Group
Further Information
Publication History
Received: 28 October 2015
Accepted after revision: 14 January 2016
Publication Date:
10 February 2016 (online)
Abstract
para-Substituted aryl prenyl ethers undergo a deprenylation reaction upon microwave irradiation. This offers the opportunity to use a prenyl ether as a thermolabile protecting group in the synthesis of natural products with a chromone structure, which proceeds via a tandem deprenylation/6-endo-cyclization sequence.
Supporting Information
- Supporting information for this article is available online at http://dx.doi.org/10.1055/s-0035-1561366.
- Supporting Information
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