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Synthesis 2012; 44(12): 1892-1897
DOI: 10.1055/s-0031-1290949
DOI: 10.1055/s-0031-1290949
paper
Synthesis of 3-Substituted Isocoumarin Derivatives via CuI-Catalyzed Reaction of o-Bromobenzamides with 1,3-Diketones
Further Information
Publication History
Received: 14 March 2012
Accepted after revision: 30 March 2012
Publication Date:
10 May 2012 (online)
Abstract
An approach to a variety of 3-substituted isocoumarins has been developed. The reaction proceeded from o-bromobenzamide derivatives and 1,3-diketones via CuI-catalyzed reaction in DMF under the action of K3PO4 at 120 °C without ligands or additives.
Supporting Information
- for this article is available online at http://www.thieme-connect.com/ejournals/toc/synthesis.
Included are copies of spectra of compound 3a–h, 3j–k and CIF (X-ray data) of 3h.
- Supporting Information
-
References
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For example, see:
Selected examples for the synthesis of heterocycles via a copper-catalyzed one-pot process, see: