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Synfacts 2011(12): 1378-1378  
DOI: 10.1055/s-0031-1289418
Polymer-Supported Synthesis
© Georg Thieme Verlag Stuttgart ˙ New York

Oxidation with SiO2-Supported Iodoarene-RuCl3 Bifunctional Catalysts

Contributor(s): Yasuhiro Uozumi, Haifeng Zhou
X.-M. Zeng, J.-M. Chen*, K. Middleton, V. V. Zhdankin*
University of Minnesota Duluth, USA and Jiaxing University, P. R. of China
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Publication History

Publication Date:
18 November 2011 (online)

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Significance

Silica-supported iodoarene-RuCl3 bifunctional catalysts 3 and 4 were synthesized according to the scheme (1). Catalyst 3 or 4 promoted the oxidation of alcohols 5 and alkylarenes 7 in the presence of a stoichiometric amount of oxone to give the corresponding carbonyl compounds 6 and 8 in up to 98% yield (23 examples).