Ring Opening of Oxabicyclic Alkenes Catalyzed by Multinuclear
Complexes

K. Endo; K. Tanaka; M. Ogawa; T. Shibata

doi:10.1055/s-0030-1260437

Subscribe to RSS

Please copy the URL and add it into your RSS Feed Reader.

https://www.thieme-connect.de/rss/thieme/en/10.1055-s-00000131.xml

Share / Bookmark

Facebook X Linkedin Weibo

Download PDF

Synfacts 2011(6): 0644-0644
DOI: 10.1055/s-0030-1260437

Metal-Catalyzed Asymmetric Synthesis and Stereoselective Reactions

Ring Opening of Oxabicyclic Alkenes Catalyzed by Multinuclear Complexes

Contributor(s): Hisashi Yamamoto, Zhi Li
K. Endo*, K. Tanaka, M. Ogawa, T. Shibata*
Waseda Institute for Advanced Study, Tokyo and Waseda University, Tokyo, Japan

Further Information

Publication History

Publication Date:
19 May 2011 (online)

Permissions and Reprints

Significance

This paper describes a new way to accomplish the asymmetric ring opening of oxabicyclic alkene compounds with dialkyl zinc. Multinuclear Pd/Zn complexes using a BINOL derivative as ligands were proposed to be the effective catalyst. This procedure features simple ligand synthesis, high efficiency, and enantioselectivity.