Subscribe to RSS
Please copy the URL and add it into your RSS Feed Reader.
https://www.thieme-connect.de/rss/thieme/en/10.1055-s-00000131.xml
Synfacts 2010(12): 1411-1411
DOI: 10.1055/s-0030-1258862
DOI: 10.1055/s-0030-1258862
Metal-Mediated Synthesis
© Georg Thieme Verlag
Stuttgart ˙ New York
Radical Addition of Arylboronic Acids to Olefins
A. Dickschat, A. Studer*
Westfälische Wilhelms-Universität, Münster, Germany
Further Information
Publication History
Publication Date:
22 November 2010 (online)
Significance
A radical addition of arylboronic acids to various olefins is reported. The aryl radicals are generated from the boronic acid upon treatment with manganese triacetate. These radicals add to electron-poor olefins to give tetrahydronaphthalines, after renewed addition and subsequent homolytic aromatic substitution. In the presence of oxygen, the radicals add to the olefin to give arylhydroxylation products.