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Synfacts 2010(12): 1406-1406
DOI: 10.1055/s-0030-1258859
DOI: 10.1055/s-0030-1258859
Metal-Mediated Synthesis
© Georg Thieme Verlag
Stuttgart ˙ New York
Allylation of Nitrosobenzene with Pinacol Allylboronates
R. E. Kyne, M. C. Ryan, L. T. Kliman, J. P. Morken*
Boston College, Chestnut Hill, USA
Further Information
Publication History
Publication Date:
22 November 2010 (online)
Significance
The addition of nitrosobenzene to pinacol allyl boronates leads to oxidative cleavage of the carbon-boron bond with a simultaneous rearrangement of the alkene substrate. The final reaction products are secondary allylic alcohols.