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Synfacts 2010(8): 0900-0900  
DOI: 10.1055/s-0030-1257813
Metal-Catalyzed Asymmetric Synthesis and Stereoselective Reactions
© Georg Thieme Verlag Stuttgart ˙ New York

Chiral Bis(oxazolinyl)phenyl Ruthenium(II) Catalysts for Asymmetric Cyclopropanation

Contributor(s): Hisashi Yamamoto, Patrick Brady
J.-i. Ito, S. Ujiie, H. Nishiyama*
Nagoya University, Japan
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Publication History

Publication Date:
22 July 2010 (online)

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Significance

The authors describe a mild and efficient method for the cyclopropanation of alkenes with α-diazoacetates using a newly developed mononuclear Phebox complex.