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Synfacts 2010(7): 0787-0787  
DOI: 10.1055/s-0029-1220108
Metal-Catalyzed Asymmetric Synthesis and Stereoselective Reactions
© Georg Thieme Verlag Stuttgart ˙ New York

Asymmetric QuinoxP*˙Silver(I)-Catalyzed Nitroso Aldol Reaction

Contributor(s): Hisashi Yamamoto, Kimberly Griffin
A. Yanagisawa*, S. Takeshita, Y. Izumi, K. Yoshida
Chiba University, Japan
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Publication History

Publication Date:
22 June 2010 (online)

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Significance

The authors report a convenient method for the synthesis of α-aminooxy and ;α-hydroxyamino carbonyl compounds using tin and silver catalysts. The regio- and enantioselectivity is significantly higher compared to other available methods.