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Synfacts 2010(3): 0324-0324
DOI: 10.1055/s-0029-1219321
DOI: 10.1055/s-0029-1219321
Metal-Catalyzed Asymmetric Synthesis and Stereoselective Reactions
© Georg Thieme Verlag
Stuttgart ˙ New York
Rhodium(II) Carboxamidate Catalyzed Hetero-Diels-Alder Reaction of Rawal’s Diene
Y. Watanabe, T. Washio, N. Shimada, M. Anada, S. Hashimoto*
Hokkaido University, Sapporo, Japan
Further Information
Publication History
Publication Date:
18 February 2010 (online)
Significance
The chiral dirhodium(II) carboxamidate complex catalyzed hetero-Diels-Alder reaction between Rawal’s diene and aldehydes is developed with high yields and enantioselectivities. Comparing with the previous state of the art, the TADDOL-catalyzed reactions, this new method is very attractive for its low catalyst loading and short reaction time.