Synfacts 2010(3): 0303-0303  
DOI: 10.1055/s-0029-1219272
Synthesis of Materials and Unnatural Products
© Georg Thieme Verlag Stuttgart ˙ New York

Macrocyclic Polycations Made to Order

Contributor(s): Timothy M. Swager
H. M. Colquhoun*, B. W. Greenland, Z. Zhu, J. S. Shaw, C. J. Cardin, S. Burattini, J. M. Elliott, S. Basu, T. B. Gasa, J. F. Stoddart*
University of Reading, UK and Northeastern University, Evanston, USA
Further Information

Publication History

Publication Date:
18 February 2010 (online)

Significance

The cationic 4,4′-bipyridinium group is one of the most effective units to create functional rotaxane structures. This work shows a general synthesis of highly rigid materials and initial demonstrations of their ability to complex neutral donor molecules and charged molecules with complementary charge.