Rhodium-Catalyzed Asymmetric Conjugate Addition of Alkenylstannanes

S. J. Mahoney; A. M. Dumas; E. Fillion

doi:10.1055/s-0029-1219140

Subscribe to RSS

Please copy the URL and add it into your RSS Feed Reader.

https://www.thieme-connect.de/rss/thieme/en/10.1055-s-00000131.xml

Share / Bookmark

Facebook X Linkedin Weibo

Download PDF

Synfacts 2010(2): 0190-0190
DOI: 10.1055/s-0029-1219140

Metal-Catalyzed Asymmetric Synthesis and Stereoselective Reactions

Rhodium-Catalyzed Asymmetric Conjugate Addition of Alkenylstannanes

Contributor(s): Mark Lautens, David A. Candito
S. J. Mahoney, A. M. Dumas, E. Fillion*
University of Waterloo, Canada

Further Information

Publication History

Publication Date:
21 January 2010 (online)

Permissions and Reprints

Significance

The use of alkenylstannes as nucleophiles in metal-catalyzed asymmetric conjugate additions can provide several advantages over other pronucleophiles in terms of functional group tolerance and ease of preparation. The authors report the first examples of enantioselective conjugate additions of alkenylstannanes.