Direct Conversion of Carbon-Hydrogen
into Carbon-Carbon Bonds by First-Row Transition-Metal
Catalysis

Amol A. Kulkarni; Olafs Daugulis

doi:10.1055/s-0029-1217131

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Synthesis 2009(24): 4087-4109
DOI: 10.1055/s-0029-1217131

REVIEW

Direct Conversion of Carbon-Hydrogen into Carbon-Carbon Bonds by First-Row Transition-Metal Catalysis

Amol A. Kulkarni, Olafs Daugulis*
Department of Chemistry, University of Houston, Houston, TX 77204-5003, USA
Fax: +1(713)7432701; e-Mail: olafs@uh.edu;

Further Information

Publication History

Received 4 August 2009
Publication Date:
20 November 2009 (online)

Abstract
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Abstract

This review summarizes first-row transition-metal catalysis for the conversion of carbon-hydrogen into carbon-carbon bonds. In particular, catalysis by manganese, iron, cobalt, copper, and nickel is covered. These metals are abundant in the Earth’s crust but so far they have been comparatively underutilized in carbon-hydrogen bond-functionalization reactions.

1 Introduction

2 Manganese-Mediated C-H Bond Functionalization

3 Iron-Mediated C-H Bond Functionalization

4 Cobalt-Mediated C-H Bond Functionalization

4.1 Directed C-H Bond Functionalization

4.2 Functionalization of the Aldehyde C-H Bond

4.3 Tandem C-H Activation/Enyne-Cyclization Reactions

4.4 Functionalization of sp^³ C-H Bonds

5 Copper-Mediated C-H Bond Functionalization

6 Nickel in C-H Bond Functionalization

7 Concluding Remarks

Key words

iron - cobalt - copper - manganese - nickel - C-H activation

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