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Synthesis 2009(11): 1909-1915  
DOI: 10.1055/s-0029-1216789
PAPER
© Georg Thieme Verlag Stuttgart ˙ New York

Micellar Solution of Sodium Dodecyl Sulfate (SDS) Catalyzes Kabacknik-Fields Reaction in Aqueous Media

Sara Sobhani*, Asieh Vafaee
Department of Chemistry, College of Sciences, Birjand University, Birjand 414, Iran
Fax: +98(561)2502009; e-Mail: ssobhani@birjand.ac.ir; e-Mail: sobhanisara@yahoo.com;
Further Information

Publication History

Received 30 January 2009
Publication Date:
30 April 2009 (online)

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Abstract

A new, convenient and high-yielding procedure for the one-pot synthesis of diethyl α-aminophosphonates from aldehydes, amines and diethyl phosphite (Kabacknik-Fields reaction) in SDS micellar solution in aqueous media is described. The synthesis of α-aminophosphonates in the present study represents a three-component reaction in which no intermediate formation of either an imine or α-hydroxyphosphonate was observed.

Key words

aldehydes - amines - α-aminophosphonates - micelles - sodium dodecyl sulfate - aqueous media

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