Cross-Coupling Reactions Between Alkynyl Metals and (Pseudo)Halides Induced by Earth-Abundant Transition Metals (Mn, Fe, Co, Ni, Cu)

Janine Cossy

doi:10.1055/a-2626-7083

Synthesis, Table of Contents

Synthesis 2025; 57(21): 3031-3048
DOI: 10.1055/a-2626-7083

Review

Published as part of the Special Topic Dedicated to Prof. Paul Knochel

Cross-Coupling Reactions Between Alkynyl Metals and (Pseudo)Halides Induced by Earth-Abundant Transition Metals (Mn, Fe, Co, Ni, Cu)

Authors

Janine Cossy

ESPCI Paris, Paris, France (Ringgold ID: RIN52883)

Abstract

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Dedication

Dedicated to Professor Paul Knochel on the occasion of his 70th birthday.

Abstract

In this review, we describe the synthesis of substituted alkynes by C–C bond formation, using cross-coupling reactions between alkynyl metals (alkynyl Grignard reagents and alkynyl zinc derivatives) with (pseudo)halides, catalyzed by abundant and inexpensive transition metals such as manganese, iron, cobalt, nickel, and copper. These cross-coupling reactions are chemo- and stereoselective.

Keywords

Alkynyl Grignard reagents - Alkynylzinc derivatives - (Pseudo)halides - Cross-couplings - Transition metals

Full Text

References

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