Comparative Investigation of Electrocatalytic Oxidation of Cyclohexene by Proton-Exchange Membrane and Anion-Exchange Membrane Electrolyzers

Yuto Ido; Yugo Shimizu; Naoki Shida; Mahito Atobe

doi:10.1055/a-2000-8231

Synthesis, Table of Contents

Synthesis 2023; 55(18): 2979-2984
DOI: 10.1055/a-2000-8231

paper

Special Issue Electrochemical Organic Synthesis

Comparative Investigation of Electrocatalytic Oxidation of Cyclohexene by Proton-Exchange Membrane and Anion-Exchange Membrane Electrolyzers

Yuto Ido

^aDepartment of Chemistry and Life Science, Yokohama National University, 79-5 Tokiwadai, Hodogaya-ku, Yokohama 240-8501, Japan

,

Yugo Shimizu

^aDepartment of Chemistry and Life Science, Yokohama National University, 79-5 Tokiwadai, Hodogaya-ku, Yokohama 240-8501, Japan

,

Naoki Shida∗

^aDepartment of Chemistry and Life Science, Yokohama National University, 79-5 Tokiwadai, Hodogaya-ku, Yokohama 240-8501, Japan

^bAdvanced Chemical Energy Research Center, Yokohama National University, 79-5 Tokiwadai, Hodogaya-ku, Yokohama 240-8501, Japan

,

Mahito Atobe ∗

^aDepartment of Chemistry and Life Science, Yokohama National University, 79-5 Tokiwadai, Hodogaya-ku, Yokohama 240-8501, Japan

^bAdvanced Chemical Energy Research Center, Yokohama National University, 79-5 Tokiwadai, Hodogaya-ku, Yokohama 240-8501, Japan

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Abstract

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Abstract

Electrocatalytic oxidation of cyclohexene was performed in proton-exchange membrane (PEM) and anion-exchange membrane (AEM) electrolyzers. For the efficient electrocatalytic oxidation, the anode catalyst material, applied potential, and solvent used were optimized. In addition, the differences in reactivity between the PEM and AEM electrolyzers were clarified and a mechanism for the oxidation of cyclohexene in each electrolyzer was proposed.

Key words

electrocatalytic oxidation - proton-exchange membrane electrolyzer - anion-exchange membrane electrolyzer - cyclohexene

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References

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