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Synlett 2022; 33(06): 518-530
DOI: 10.1055/a-1679-8141
DOI: 10.1055/a-1679-8141
account
Resorcinarene-Based Supramolecular Capsules: Supramolecular Functions and Applications
This work was supported by Grants-in-Aid for Scientific Research (A), JSPS KAKENHI (21H04685), Grants-in-Aid for Scientific Research (C) (18K05085), Grants-in-Aid for Challenging Exploratory Research, JSPS KAKENHI (20K21196, 21K19009), and Grants-in-Aid for Transformative Research Area (A), JSPS KAKENHI (Condensed Conjugation, 21H05491). Funding from The Urakami Scholarship Foundation, the Eno Scientific Foundation, and Iketani Science and Technology Foundation is gratefully acknowledged.
Abstract
A resorcinarene is a synthetic macrocycle consisting of four resorcinol molecules covalently linked by methylene bridges. The interannular bridges produce a cavitand that has a bowl-shaped structure. We have developed supramolecular capsules through Ag(I) or Cu(I) coordination-driven self-assembly of cavitands possessing 2,2′-bipyridyl arms in their upper rims. The self-assembled capsules accommodate various molecular guests and supramolecular assemblies possessing acetoxy groups. The host–guest chemistry of the molecular capsules has been applied in the fabrication of supramolecular polymers. This account describes recent developments in the supramolecular chemistry of resorcinarene-based coordination capsules and provides a brief history of resorcinarene-based capsules and related capsules.
Key words
supramolecular chemistry - host–guest chemistry - resorcinarenes - molecular capsules - molecular recognition - self-assemblyPublication History
Received: 19 October 2021
Accepted after revision: 27 October 2021
Accepted Manuscript online:
27 October 2021
Article published online:
17 December 2021
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