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Synthesis 2021; 53(16): 2889-2896
DOI: 10.1055/a-1488-4467
DOI: 10.1055/a-1488-4467
paper
Yb(OTf)3-Mediated Regioselective Hydroamination of Ynamides with Anilines and p-Toluenesulfonamide
This study was supported by National College Students Innovation and Entrepreneurship Training Program (202010304044Z), the Jiangsu’s Mass Entrepreneurship and Innovation Program, the Start-Up Funding for Research of Nantong University (03081231), and the Large Instruments Open Foundation of Nantong University (KFJN2175; KFJN2176).
Abstract
A rare-earth salt Yb(OTf)3-catalyzed regioselective hydroamination of ynamides with anilines and p-toluenesulfonamide has been developed. This protocol provided facile access to a diverse range of amidines with good functional group tolerance in moderate to high yields.
Supporting Information
- Supporting information for this article is available online at https://doi.org/10.1055/a-1488-4467.
- Supporting Information
Publication History
Received: 23 March 2021
Accepted after revision: 21 April 2021
Accepted Manuscript online:
21 April 2021
Article published online:
19 May 2021
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