A similar observation where the chemoselectivity is controlled by the reaction temperature (25 °C vs. 100 °C) was made by Stephan and co-workers before: Perez M. Qu Z.-W. Caputo CB. Podgorny V. Hounjet LJ. Hansen A. Dobrovetsky R. Grimme S. Stephan DW.
Chem. Eur. J. 2015;
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