DOI: 10.1055/s-00000084

Synthesis

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Huang studied the mechanism for Rh(I)-catalyzed cyclization of allenyne through C(sp3)–H bond activation (ref. 2) by means of DFT calculation. According to this work, the cyclization proceeded through metal-assisted σ-bond metathesis like rhoda­cycle iv, see: Huang G.
Org. Lett. 2015;
17: 1994

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