Synfacts
Issue 04 · April 2018
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A47
SYNFORM
ISSUE 2018/04
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Synthesis of Natural Products and Potential Drugs
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0331
Synthesis of Aminocyclohexenes from 7-Azanorbornenes
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0332
Synthesis of Canagliflozin
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0333
Syntheses of Plakortin Polyketides
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0334
Enantioselective Total Synthesis of (–)-α-Cyclopiazonic Acid
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0335
Synthesis of Histone Acetyltransferase Inhibitor A-485
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0336
Synthesis of Δ
9
-Tetrahydrocannabinol
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0337
Synthesis of (+)-Pleuromutilin
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0338
Synthesis of BMS-986118
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0339
Synthesis of Arboridinine
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0340
Synthesis of PF-06815189
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0341
Total Syntheses of Stephacidin Congeners
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0342
Modular Synthesis of Bisquinolizidine Alkaloids
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0343
Asymmetric Alkynylation in the Synthesis of Efavirenz Intermediates
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0344
Enantioselective Synthesis of (+)-Astellatol
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0345
Synthesis of M-525
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Synthesis of Heterocycles
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0347
Cooperative Amine–Copper Catalysis
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0348
Gold-Catalyzed Synthesis of Isoxazole-Fused Heterocycles
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0349
Benzannulated Heterocycles by Aza-Claisen Rearrangement
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0350
Palladium-Catalyzed Amination of Chloroheteroarenes with Secondary Amines
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0351
Dehydrogenative Cyclization of 8-Amido-quinolines
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0352
Minisci Alkylation of Heteroarenes with Boronic Acids
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0353
Catalytic Pummerer Reaction Approach to 3-Thiofurans and 3-Thiobenzofurans
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0354
Synthesis of γ-Lactams by Radical-Induced 1,6-Enyne Cyclization
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0355
3,4-Dihydroisoquinolines by Photooxidative Annulation of Imines with Alkenes
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0356
α-Functionalization of Unprotected Cyclic Amines by Hydride Abstraction
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0357
Facile Access to Dihydrocoumarins through Catalytic Hydroarylation
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0358
Electrochemical Synthesis of Imidazo-Fused Heterocycles
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0359
Tetrahydropyridines from Condensation of Sulfonamidoenones with
N
-Sulfonylimines
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0360
Synthesis of Spirocyclic Pyrido- and Pyrroloquinolines from an Isatin Derivative
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Synthesis of Materials and Unnatural Products
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0361
Chemical Cubism: Cubanes Cross-Coupled to Chromophores and More
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0362
Heterocyclic Fluorophores via Grignard Chemistry
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0363
Annulative Dimerization of Chloroarenes Gives Fused Aromatics
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0364
Facile, Mild Access to Polydiquinolineanthracene
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0365
Green and Gold: Au Catalysis Improves Iododeboronation Scope
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0366
Rotaxane Polymer Shines under Stress
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0367
Luminescent Polymers Know Self-Defense
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0368
Dual Vicinal Functionalization Cascade of Indoles
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0369
Synthesis of Disubstituted Dihydrofuran-Fused Fullerenes
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0370
π-Extension Through the Catellani Reaction
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0371
Synthesis of Fused Nanohoops
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0372
Adding Space and Dimension to Tetrathiafulvalenes
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Metal-Catalyzed Asymmetric Synthesis and Stereoselective Reactions
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0373
Iridium-Catalyzed Regio- and Enantioselective Amination
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0374
Manganese-Catalyzed Oxidative Kinetic Resolution of Heterocyclic Sulfoxides
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0375
Tetrahydrofuroindoles by a Palladium-Catalyzed Asymmetric Dearomatization
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0376
AgSbF
6
-Catalyzed Tandem Rearrangement/Friedel–Crafts Alkylation
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0377
Regioselective Silylation: Synthesis of 1,2-Diols
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0378
Regioselective Silylation: Synthesis of 1,4-Diols
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0379
Stereodivergent Allylation of Azaaryl Acetamides/Acetates
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0380
Asymmetric Alkynylation of Ketimines
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0381
The First Useful Planar Chiral dbCOT-Ligands
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0382
Enantioselective Copper-Catalyzed Mannich-Type Reaction
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0383
Enantioselective Direct Aldol Reaction of α-Vinylated Thioamides
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0384
Rhodium-Catalyzed Hydrogenation–Desymmetrization of Cyclohexadienones
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0385
Zinc-Catalyzed Synthesis of 8-Oxabicyclo-[3.2.1]octanes
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0386
Asymmetric Perfluoroalkylation of β-Keto Esters by Nickel/Photoredox Catalysis
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0387
Copper-Catalyzed Enantioselective Allylation of Ketones
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0388
Rhodium-Catalyzed Asymmetric Enyne Cycloisomerization
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0389
Palladium-Catalyzed Asymmetric Synthesis of Oxazolines
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0390
Asymmetric Hydrogenation of Amino-containing Phenanthrenes
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0391
Cooperative Effect Ensures Efficient Aza-Wacker Reaction
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0392
α-Arylation of Cyclobutanones through Synergistic Palladium/Enamine Catalysis
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0393
Asymmetric Synthesis of α-Substituted α-Amino Acids and α-Amino Amides
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0394
Regio- and Diastereoselective Synthesis of Isoxazolidines
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0395
Cycloaddition of Azomethine Ylides with Benzo[
b
]thiophene Sulfones
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0396
Iridium-Catalyzed Enantioselective Reduction of Heteroaryl Ketones
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0397
Palladium-Catalyzed Formal [3+2] Annulation
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0398
Palladium-Catalyzed Enantioselective Cycloaddition of Vinyloxetanes
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0399
‘Chiral-at-Metal’ Asymmetric Conjugate Addition of 2-Acylimidazoles
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0400
Manganese-Catalyzed Selective Hydrosilylation of Alkynes
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0401
Enantioselective Copper-Catalyzed Borylation–Addition to Fluoroalkyl Ketones
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0402
P-Stereogenic Products by Hydroarylation of Divinylphosphine Oxides
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Metal-Mediated Synthesis
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0403
Dual Photoredox/Nickel-Catalysis for the Cross-coupling of Aziridines
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0404
Amide Synthesis Using Ynones as Acylation Agents
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0405
Addition of Lithiated Dithianes to the Autoxidized Counterpart
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0406
Construction of Quinazolines via Iron-Catalyzed Amination
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0407
Diastereoselective Synthesis of Alkenyl Boronates
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0408
Mn(II)Cl
2
-Catalyzed Stille Cross-Couplings
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0409
Regioselective Hydroboration of Aryl Alkenes
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0410
Nickel-Catalyzed Synthesis of 3,3-Disubstituted Oxindoles
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0411
Highly Efficient Barbier–Negishi Coupling of Secondary Alkyl Bromides
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0412
New Photoinduced Meerwein-Type Arylation
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0413
α,β-Dehydrogenation of Cyclic Ketones
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0414
Bench-Stable Solid Triorganoindium Reagents
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0415
Radical Polar Crossover Reaction of Vinyl Boron Ate Complexes
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0416
Inert C–O Bond Functionalization Using an Organo Rare-Earth Metal Complex
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0417
Difluoroalkylation and Trifluoromethylchalcogenation
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Organo- and Biocatalysis
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0419
Chemoenzymatic Distal C–H Hydroxylation
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0420
Supramolecular Brønsted Acid Catalyzed Carbonyl–Olefin Metathesis
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0421
Phosphine Oxide-Catalyzed γ-Umpolung Addition–Wittig Olefination
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0422
Sulfide-Catalyzed Cross-Coupling of Benzyl Halides and Boronic Acids
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0423
Purine Nucleoside Synthesis by Three-Component Dynamic Kinetic Resolution
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0424
β-Alkylation of Enals by Excited-State Iminium Catalysis
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0425
Site-Selective Oxidation of Macrolactones with a Single Biocatalyst
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0426
Construction of Halogenated Quaternary Carbon Centers
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0427
Bisguanidinium-Controlled Asymmetric Rearrangements of Acylsilanes
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0428
Desymmetrizing Asymmetric Selenoetherification
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Polymer-Supported Synthesis
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0429
Racemization of Tertiary Alcohols on Acidic Resins
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0430
Reduction of Nitroarenes on Palladium/Nickel-Doped Iron Nanoparticles
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0431
Suzuki–Miyaura Reaction Catalyzed by Cage-Templated Palladium Nanoparticles
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0432
One-Pot Aza-Friedel–Crafts Reaction on Amberlyst 15-Supported Silicotungstic Acid
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0433
Heterobimetallic Catalysis: Access to Trifluormethylated
vic
-Amino Alcohols
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0434
Hydrolysis of BH
3
·NH
3
and Synthesis of Quina-zolines Catalyzed by Ni–Pd Nanoparticles
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0435
Mesoporous Polymer Supported Gold(I) Catalysts
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0436
Photocatalyzed Reduction of Azides to Amines
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0437
An Imidazolium-Functionalized Metal–Organic Framework for Fixation of CO
2
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0438
Suzuki–Miyaura Cross-Coupling on a Palladium/Melamine–Cyanurate Catalyst
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0439
C–H Acylation of Phenylpyrazoles on Kaolin-Supported Palladium Nanoparticles
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0440
Cu(II) Metal–Organic Framework Catalyst for Cycloaddition of CO
2
to Epoxides
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0441
Synthesis of Triazole[1,2-
a
]indazoletriones on Silica-Coated Zinc Oxide
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0442
Huisgen Cycloaddition Catalyzed by Hydro-talcite-Supported Copper Nanoparticles
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0443
Supported Cobalt Nanoparticles for Catalytic Reduction of Aldehydes by Formic Acid
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