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DOI: 10.1055/s-2003-42777
Germacrane Sesquiterpene Esters from Salvia roborowskii
Publication History
Received: November 26, 2002
Accepted: March 9, 2003
Publication Date:
06 October 2003 (online)

Abstract
From the whole plant of Salvia roborowskii, four new germacrane sesquiterpene esters, 3β,6β,8α-triacetoxy-4β,5α-epoxy-1-oxogermacr-10(14)-ene, 3β,6β,8α-triacetoxy-4β,5α-epoxygermacr-1 (10)E-ene, 3β,6β,8α-triacetoxy-4β,5α:1α,10β-diepoxygermacrane and 6β-acetoxyglechomafuran were isolated, and their structures were elucidated by spectroscopic methods including 2D NMR techniques (1H-1H COSY and 1H-1H NOESY for 1).
References
- 1 Name Reference of Chinese herbal medicine of the whole country. People’s Health Press Beijing; 1996: p. 938
- 2 Wang S F, Li S, Li Z G, Li Y. Triterpenoids and other compounds from Salvia roborowskii Maxim. Pharmazie. 2001; 56 420-2
- 3 Miski M, Moubasher H A, Mabry T J. Sesquiterpene aryl esters from Ferulago antiochia . Phytochemistry. 1990; 29 881-6
- 4 Hayashi K I, Asano K I, Tanaka M, Takaoka D, Nozaki H. Biotransformation of shiromodiol diacetate, myli-4(15)-en-9-one and myliol by Aspergillus niger . Phytochemistry. 1998; 48 461-6
- 5 Shi Y P, Guo W, Jia Z J. Germacranolides from Carpesium lipskyi . Planta Med. 1999; 65 94-6
- 6 Barrero A F, Herrador M M, Quilez J F, Manzaneda R A, Portal D olores, Gavin J A, Gravalos D G, Simmonds M SJ, Blaney W M. Bioactive sesquiterpenes from Santolina rosmarinifolia subsp. canescens. A conformational analysis of the germacrane ring. Phytochemistry. 1999; 51 529-41
- 7 Ulubelen A, ÖKsüz S. Relative configuration of glechomafuran isolated from the fruits of Smyrnium olusatrum . J Nat Prod. 1983; 46 490-2
- 8 Ulubelen A, Gören N, Bohlmann F, Jakupovic J, Grenz M, Tanker N. Sesquiterpene lactones from Smyrnium cordifolium . Phytochemistry. 1985 ; 24 1305-8
Prof. Yan-Ping Shi
Lanzhou Institute of Chemical Physics
Chinese Academy of Sciences
Lanzhou
Gansu 730000
Peoples Republic of China
Fax: +86-931-8277088
Email: shiyp@lzu.edu.cn or shiyp@ns.lzb.ac.cn