Ethenesulfonyl Fluoride (ESF) and Its Derivatives in SuFEx Click Chemistry and More

Yan-Ping Meng; Shi-Meng Wang; Wan-Yin Fang; Zhi-Zhong Xie; Jing Leng; Hamed Alsulami; Hua-Li Qin

doi:10.1055/s-0039-1690038

Synthesis, Table of Contents

Synthesis 2020; 52(05): 673-687
DOI: 10.1055/s-0039-1690038

short review

Ethenesulfonyl Fluoride (ESF) and Its Derivatives in SuFEx Click Chemistry and More

Authors

Yan-Ping Meng

^aSchool of Chemistry, Chemical Engineering and Life Science, Wuhan University of Technology, 205 Luoshi Road, Wuhan, Hubei Province, 430070, P. R. of China Email: qinhuali@whut.edu.cn
Shi-Meng Wang∗

^aSchool of Chemistry, Chemical Engineering and Life Science, Wuhan University of Technology, 205 Luoshi Road, Wuhan, Hubei Province, 430070, P. R. of China Email: qinhuali@whut.edu.cn

^bSchool of Materials Science and Engineering, Wuhan University of Technology, 205 Luoshi Road, Wuhan, Hubei Province, 430070, P. R. of China
Wan-Yin Fang

^aSchool of Chemistry, Chemical Engineering and Life Science, Wuhan University of Technology, 205 Luoshi Road, Wuhan, Hubei Province, 430070, P. R. of China Email: qinhuali@whut.edu.cn

^bSchool of Materials Science and Engineering, Wuhan University of Technology, 205 Luoshi Road, Wuhan, Hubei Province, 430070, P. R. of China
Zhi-Zhong Xie∗

^aSchool of Chemistry, Chemical Engineering and Life Science, Wuhan University of Technology, 205 Luoshi Road, Wuhan, Hubei Province, 430070, P. R. of China Email: qinhuali@whut.edu.cn
Jing Leng

^aSchool of Chemistry, Chemical Engineering and Life Science, Wuhan University of Technology, 205 Luoshi Road, Wuhan, Hubei Province, 430070, P. R. of China Email: qinhuali@whut.edu.cn

^bSchool of Materials Science and Engineering, Wuhan University of Technology, 205 Luoshi Road, Wuhan, Hubei Province, 430070, P. R. of China
Hamed Alsulami

^cDepartment of Mathematics, Faculty of Science, King Abdulaziz University, P.O. Box 80203, Jeddah 21589, Saudi Arabia
Hua-Li Qin∗

^aSchool of Chemistry, Chemical Engineering and Life Science, Wuhan University of Technology, 205 Luoshi Road, Wuhan, Hubei Province, 430070, P. R. of China Email: qinhuali@whut.edu.cn

^bSchool of Materials Science and Engineering, Wuhan University of Technology, 205 Luoshi Road, Wuhan, Hubei Province, 430070, P. R. of China

Abstract

All articles of this category

Abstract

The sulfur(VI) fluoride exchange reaction (SuFEx), developed by Sharpless and co-workers in 2014, is a new category of click reaction that creates molecular connections with absolute reliability and unprecedented efficiency through a sulfur(VI) hub. Ethenesulfonyl fluoride (ESF), as one of the most important sulfur(VI) hubs, exhibits extraordinary reactivity in SuFEx click chemistry and organic synthesis. This review summarizes the chemical properties and applications of ESF in click chemistry, organic chemistry, materials science, medicinal chemistry and in many other fields related to organic synthesis.

1 Introduction

2 Chemical Transformations of ESF

3 Chemical Transformations of 2-Arylethenesulfonyl Fluorides

4 Novel SuFEx Reagents Derived from ESF

5 Applications of ESF Derivatives in Medicinal Chemistry

6 Applications of ESF Derivatives in Materials Science

7 Conclusion

Key words

sulfur(VI) fluoride exchange - ethenesulfonyl fluoride - 2-arylethenesulfonyl fluorides - sulfur(VI)-based molecules - medicinal chemistry - materials science

Full Text

References

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