Synthesis, Table of Contents Synthesis 2019; 51(02): 557-563DOI: 10.1055/s-0037-1610831 paper © Georg Thieme Verlag Stuttgart · New YorkSynthesis and Optical Resolution of 3,3,3′,3′-Tetramethyl-1,1′-spirobiindane-7,7′-diol Authors Author Affiliations Qiaoxia Zhou Rihuang Pan Huanyu Shan Xufeng Lin * Laboratory of Asymmetric Catalysis and Synthesis, Department of Chemistry, Zhejiang University, Hangzhou 310027, P. R. of China Email: lxfok@zju.edu.cn Recommend Article Abstract Buy Article(opens in new window) All articles of this category(opens in new window) Abstract A novel chiral C2-symmetric spiro diol, 3,3,3′,3′-tetramethyl-1,1′-spirobiindane-7,7′-diol (TMSIOL), was conveniently prepared via practical seven-step route from Bisphenol A in 45.1% overall yield. l-Menthyl chloroformate is used as optical resolving agent for the separation of the two enantiomers of TMSIOL. 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