Synthesis, Table of Contents Synthesis 2017; 49(23): 5224-5230DOI: 10.1055/s-0036-1588546 paper © Georg Thieme Verlag Stuttgart · New YorkTf2NH-Catalyzed 1,6-Conjugate Addition of Vinyl Azides with p-Quinone Methides: A Mild and Efficient Method for the Synthesis of β-Bis-Arylamides Authors Author Affiliations Jayant Rathod a Division of Organic Chemistry, CSIR-National Chemical Laboratory, Dr. Homi Bhabha Road, Pune-411008, India Email: pk.tripathi@ncl.res.in b Academy of Scientific and Innovative Research (AcSIR), New Delhi-110025, India Brijesh M. Sharma a Division of Organic Chemistry, CSIR-National Chemical Laboratory, Dr. Homi Bhabha Road, Pune-411008, India Email: pk.tripathi@ncl.res.in b Academy of Scientific and Innovative Research (AcSIR), New Delhi-110025, India Pramod S. Mali c Central NMR Facility, National Chemical Laboratory, Pune-411008, India Pradeep Kumar* a Division of Organic Chemistry, CSIR-National Chemical Laboratory, Dr. Homi Bhabha Road, Pune-411008, India Email: pk.tripathi@ncl.res.in b Academy of Scientific and Innovative Research (AcSIR), New Delhi-110025, India Recommend Article Abstract Buy Article(opens in new window) All articles of this category(opens in new window) Abstract Tf2NH-catalyzed tandem 1,6-conjugate addition/Schmidt type rearrangement using vinyl azides and p-quinone methides to access a variety of β-bis-arylated amides is reported. The method is quick, efficient, mild, and high yielding with broad substrate scope. Key words Key wordsvinyl azide - p-quinone methide - Brønsted acid - 1,6-conjugate addition - rearrangement - β-bis-arylamides Full Text References References 1a Parella R. Gopalakrishnan B. Arulananda Babu S. J. Org. Chem. 2013; 78: 11911 1b Mu D. Gao F. Chen G. He G. ACS Catal. 2017; 7: 1880 1c Yang X. 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